Contra-electronegativity Transmetalation Unlocks Alkene Carbomagnesiation to Access Quaternary Stereocenters

Regio- and Enantioselective Intermolecular Carbo-halogenation of Alkenes via Nickel/N-Heterocyclic Carbene Catalysis

Dynamic Kinetic Asymmetric Allylation of Ketones: Stereodivergent Synthesis of E- or Z-Substituted α,β-Stereogenic Tertiary Alcoho

Enantioselective Reductive Heck and Heck Coupling of Internal Cyclic Alkenes Enabled by Nickel/N‑Heterocyclic Carbene Catalysis

Enantioselective Pd-Catalyzed Alkene Carbothiolation via C-S Bond Activation to Form Indole Derivatives with Quaternary Stereocenters

Enantio- and Diastereoselective NHC/Ni-Catalyzed Reductive Coupling of Alkenes with Carbonyls: Synthesis of Optically Active Indanols

Enantio- and diastereoselective NHC/Cu-catalyzed intermolecular dearomative cyclopropanation of indoles with diazo esters

Enantioconvergent Negishi Cross-Coupling of Racemic sec-Alkylzinc Reagent with Aryl Halides Enabled by Bulky N-Heterocyclic Carbene-Pd Catalyst

Ni-Catalyzed Addition of Arylborons to Alkenes for the Synthesis of Quaternary Carbon Centers

Selective Dynamic Kinetic Asymmetric Aldehyde-Alkyne Reductive Coupling

NHC/nickel-catalyzed asymmetric hydroarylation reaction of vinyl ethers

Progress on Chiral N‑Heterocyclic Carbene‑Metal Catalyzed Asymmetric Carbonyl Addition Reactions