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科研成果

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Reversible complexation of isocyanides by the distannyne Ar'SnSnAr' (Ar' = C6H3-2,6(C6H3-2,6-iPr2)

Y. Peng, X. Wang, J. C. Fettinger, P. P. Power*

Chem. Commun 2010, 46, 943
Synthesis and Characterization of the M(II) (M = Ge, Sn, or Pb) Phosphinidene Dimers {M(μ-PAr')}2(Ar' = C6H3-2, 6-(C6H3-2, 6-Pri2)2)

W. Merrill, E. Rivard, JS DeRopp, X. Wang, B. Ellis, J. Fettinger, B. Wrackmeyer, P. P. Power

Inorg. Chem 2010, 49, 8481-8486
An unsymmetric oxo/imido bridged germanium-centered singlet diradicaloid

X. Wang, Y. Peng, J. C. Fettinger, M. Olmstead, P . P. Power*

J. Am. Chem. Soc 2009, 131, 14164 – 14165
Room-temperature reaction of carbon monoxide with a stable diarylgermylene

X. Wang, Z. Zhu, Y. Peng, H. Lei, J. C. Fettinger, P. P. Power*

J. Am. Chem. Soc 2009, 131, 6912 - 6913
N-H and N=C bond formation via germanium (III) diradicaloid intermediates and C-S Bond cleavage in reactions of the digermyne Ar'GeGeAr' (Ar' = C6H3-2, 6-(C6H3-2, 6-Pri2)2) with azides

X. Wang, C. Ni, Z. Zhu, J. C. Fettinger, P. P. Power*

Inorg. Chem 2009, 48, 2464 - 2470
Synthesis and characterization of [Ar'GaC(Ph)CH]2 and K2[Ar'GaC(Ph)CH]2.OEt2: from digallene to digallacyclohexadiene to digallabenzene

Z. Zhu, X. Wang, M. M. Olmstead, P. P. Power*

Angew. Chem. Int. Ed 2009, 48, 2027 - 2030
Addition of hydrogen or ammonia to a low-valent group 13 metal species at 25oC and 1 atmosphere

Z. Zhu, X. Wang, Y. Peng, H. Lei, J. C. Fettinger, E. Rivard, P. P. Power*

Angew. Chem. Int. Ed 2009, 48, 2031 - 2034
Reversible Reactions of Ethylene with Distannynes Under Ambient Conditions

Y. Peng, B. D. Ellis, X. Wang, J. C. Fettinger, P. P. Power*

Science 2009, 325, 1668 - 1669
Silver(I) complexes of the weakly coordinating solvents SO2 and CH2Cl2: Crystal structures, bonding, and energetics of [Ag(OSO)][Al{OC(CF3)3}4], [Ag(OSO)2/2][SbF6], and [Ag(CH2Cl2)2][SbF6]

A. Decken, C. Knapp,* G. B. Nikiforov, J. Passmore*, J. M. Rautiainen, X. Wang, X. Zeng

Chem. Eur. J 2009, 15, 6504 - 6517
Diarylstannylene activation of hydrogen or ammonia with arene elimination

Y. Peng, B. D. Ellis, X. Wang, P. P. Power*

J. Am. Chem. Soc 2008, 130, 12268–12269
Cyclic Dimethylsiloxanes as Pseudo Crown Ethers: Syntheses and Characterization of Li(Me2SiO)5[Al{OC(CF3)3}4], Li(Me2SiO)6[Al{OC(CF3)3}4], and Li(Me2SiO)6[Al{OC(CF3)2Ph}4]†

Andreas Decken, Jack Passmore,* and Xinping Wang

Angew. Chem 2006, 118, 2839 –2843
Cyclodimethylsiloxanes (Me2SiO)n (n = 3 - 6) ring transformations on reactions with AgSbF6; Crystal structure of Ag(Me2SiO)7SbF6

A. Decken, F. A. LeBlanc, J. Passmore*, X. Wang

Eur. J. Inorg. Chem 2006, , 4033 - 4036

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