郑超/研究员

zhengchao@sioc.ac.cn

021-54925323

教育背景

2003.09-2007.07 上海交通大学 学士

2007.09-2012.07 中国科学院上海有机化学研究所 博士

2012.07-2015.04 中国科学院上海有机化学研究所 助理研究员

2015.04-2023.12 中国科学院上海有机化学研究所 副研究员

2023.12至今 中国科学院上海有机化学研究所 研究员

获奖及荣誉

2016年 上海市自然科学奖 一等奖(第三完成人)

2017年 国家自然科学奖二等奖(第三完成人)

2023年 国家自然科学基金委优秀青年科学基金项目

代表论著

(1)  Liu, J.; Dong, Z.; Cao, W.-B.; Zheng, C.*; You, S.-L.* Interrupting π-σ-π Isomerization Enables Z-Retentive Tsuji–Trost Reactions. J. Am. Chem. Soc. 2025, 147, 2776-2785.

(2) Wu, W.-Q.; Xie, P.-P.; Wang, L.-Y.; Gou, B.-B.; Lin, Y.; Hu, L.-W.; Zheng, C.*; You, S.-L.*; Shi, H.* Chiral Bis(binaphthyl) Cyclopentadienyl Ligands for Rhodium-Catalyzed Desymmetrization of Diarylmethanes via Selective Arene Coordination. J. Am. Chem. Soc. 2024, 146, 26630-26638.

(3) Yu, X.; Zheng, C.*; You, S.-L.* Chiral Brønsted Acid Catalyzed Intramolecular Asymmet-ric Dearomative Reaction of Indoles with Cyclobutanones via Cascade Friedel–Crafts/semipinacol Rearrangement. J. Am. Chem. Soc. 2024, 146, 25878-25887.

(4) Zhu, M.; Gao, Y.-J.; Huang, X.-L.#; Li, M.; Zheng, C.*; You, S.-L.* Photo-Induced In-tramolecular Dearomative [5 + 4] Cycloaddition of Arenes for the Construction of High-ly Strained Medium-Sized-Rings. Nat. Commun. 2024, 15, 2462.

(5) Xu, M.-M.#; Xie, P.-P.#; He, J.-X.; Zhang, Y.-Z. Zheng, C.*; Cai, Q.* Enantioselective Cross-[4 + 2]-Cycloaddition/Decarboxylation of 2-Pyrones by Cooperative Catalysis of Pd(0)/NHC Complex and Chiral Phosphoric Acid. J. Am. Chem. Soc. 2024, 146, 6936-6946.

(6) Huang, X.-Y.#; Xie, P.-P.#; Zou, L.-M.; Zheng, C.*; You, S.-L.* Asymmetric Dearomatiza-tion of Indoles with Azodicarboxylates via Cascade Electrophilic Amination/Aza-Prins Cyclization/Phenonium-like Rearrangement. J. Am. Chem. Soc. 2023, 145, 11745-11753.

(7) Zhang, W.-Y.; Wang, H.-C.; Wang, Y.; Zheng, C.*; You, S.-L.* Enantioselective Dearoma-tization of Indoles via SmI2-Mediated Reductive Coupling with Ketones. J. Am. Chem. Soc. 2023, 145, 10314-10321.

(8) Zheng, Y.; Zhang, W.-Y.; Gu, Q.; Zheng, C.*; You, S.-L.* Cobalt(III)-Catalyzed Asymmet-ric Ring-Opening of 7-Oxabenzonorbornadienes via Indole C–H Functionalization. Nat. Commun. 2023, 14, 1094.

(9) Liu, C.-X.#; Xie, P.-P.; Zhao, F.; Wang, Q.; Feng, Z.; Wang, H.; Zheng, C.*; You, S.-L.* Explicit Mechanism of Rh(I)-Catalyzed Asymmetric C–H Arylation and Facile Synthesis of Planar Chiral Ferrocenophanes. J. Am. Chem. Soc. 2023, 145, 4765-4773.

(10) Zhang, W.-W.; Wang, Q.; Zhang, S.-Z.; Zheng, C.*; You, S.-L.* Rh-Catalyzed Asymmetric Satoh–Miura-type Reactions for Building-up Axial Chirality: Counteranion Directed Switch of Reaction Pathways. Angew. Chem. Int. Ed. 2023, 62, e202214460.

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