陈耀峰 研究员 

中国科学院上海有机化学研究所

金属有机化学国家重点实验室 

上海市零陵路345号,200032

电话(传真): +86 21 54925149(64166128)

邮箱: yaofchen@sioc.ac.cn

网址http://yaofengchen.sioc.ac.cn

教育:

1996.09 - 1999.10    浙江大学高分子系,博士(导师:沈之荃院士)

1993.09 - 1996.06    杭州大学化学系,硕士(导师:龚钰秋教授)

1989.09 - 1993.06    杭州师范学院化学系本科

工作经历:

2006.02 -     中国科学院上海有机化学研究所研究员,课题组长

2003.08 - 2005.10   美国加州大学SantaBarbara分校化学系,PostdoctoralFellow

2002.10 - 2003.07   加拿大蒙特利尔大学化学系,PostdoctoralFellow

1999.12 - 2002.08   中国科学院上海有机化学研究所,博士后

研究方向:
金属有机化合物,特别是新型稀土金属有机化合物的设计,合成及催化的有机和高分子合成

职务:
课题组长

获奖及荣誉:
上海市科技进步一等奖 (排名第三)

代表论著:

1. Jiaxiang Chu, Christos E. Kefalidis, Laurent Maron,* Xuebing Leng, Yaofeng Chen,*Chameleon Behavior of a Newly Synthesized Nitrilimine Scandium DerivativeJ. Am. Chem. Soc. 2013, 135, 8165-8168.

2. Jiliang Zhou, Jiaxiang Chu, Yanyan Zhang, Guang Yang, Xuebing Leng, Yaofeng Chen,* “An Yttrium Hydride-Silane Complex as a Structural Model for a σ-Bond Metathesis Transition State” Angew. Chem. Int. Ed. 2013, 52, 4243-4246.

3. Jiaxiang Chu, Erli, Lu, Yaofeng Chen,* Xuebing Leng, “Reversible Addition of Si-H Bond of Phenylsilane to Sc=N Bond of Scandium Terminal Imido Complex” Organometallics, 2013, 32, 1137-1140. (Invited for the special issue entitled “Recent Advances in Organo-f-Element Chemistry”).

4. Yangjian Hu, Xiufang Wang, Yaofeng Chen,* Lucia Caporaso,* Luigi Cavallo,* Eugene Y.-X. Chen,* “Rare-Earth Half-Sandwich Dialkyl and Homoleptic Trialkyl Complexes for Rapid and Stereoselective Polymerization of a Conjugated Polar Olefin” Organometallics, 2013, 32, 1459-1465.

5. Erli Lu, Yuanyuan Yuan, Yaofeng Chen,* Wei Xia, “1-Methyl Boratabenzene Yttrium Alkyl: A Highly Active Catalyst for Dehydrocoupling of Me2NH×BH3 ACS Catalysis 2013, 3, 521-524. (Invited for the virtual special issue on Catalysis at SIOC).

6. Erli Lu, Qinghai Zhou, Yuxue Li, Jiaxiang Chu, Yaofeng Chen,* Xuebing Leng, Jie Sun, “Reactivity of Scandium Terminal Imido Complexes towards Metal HalidesChem. Commun. 2012, 48, 3403-3405.

7. Erli Lu, Yaofeng Chen,* Jiliang Zhou, Xuebing Leng, “CP or CH Bond Cleavage of Phosphine Oxides Mediated by an Yttrium Hydride” Organometallics, 2012, 31, 4574-4578.

8. Yilin Sun, Guangming Wu, Dinghai Cen, Yaofeng Chen,* Limin Wang,* “Synthesis and Catalytic Activity of Heterogeneous Rare-earth Metal Catalysts Coordinated with Multitopic Schiff-base Ligands” Dalton Trans., 2012, 41, 9682-9688.

9. Jiaxiang Chu, Erli Lu, Zhixiao Liu, Yaofeng Chen,* Xuebing Leng, Haibing Song “Reactivity of a Scandium Terminal Imido Complex towards Unsaturated Substrates Angew. Chem. Int. Ed. 2011, 50, 7677-7680.

10. Yingdong Lv, Xin Xu, Yaofeng Chen,* Xuebing Leng, Maxim V. BorzovWell-defined Soluble P3- Containing Rare-earth Metal Compounds Angew. Chem. Int. Ed. 2011, 50, 11227-11229.

11. Erli Lu, Jiaxiang Chu, Yaofeng Chen,* Maxim V. Borzov, Guangyu Li, “The Scandium Terminal Imido Complexes Induced C-H Bond Selenation and the Formation of Sc-Se Bond” Chem. Commun. 2011, 47, 743-745.

12. Erli Lu, Yaofeng Chen,* Xuebing Leng, “Yttrium Anilido Hydride: Synthesis, Structure, and Reactivity” Organometallics, 2011, 30, 5433-5441.

13. Yuanyuan Yuan, Xiufang Wang, Yuxue Li, Liyan Fan, Xin Xu, Yaofeng Chen,* Guangyu Li, Wei Xia, “Rapid Entry to Functionalized Boratabenzene Complexes Through Metal Induced Hydroboration at Anionic 1-H-Boratabenzene LigandOrganometallics 2011, 30, 4330-4341.

14. Peng Cui, Yaofeng Chen,* Guangyu Li, Wei Xia, “Versatile Reactivities of ansa-Heteroborabenzene Divalent Ytterbium Amide toward Alkali-Metal Salts and the Generation of Heterometallic Ytterbium-Alkali-Metal Boratabenzene Complexes” Organometallics 2011, 30, 2012-2017.

15. Erli Lu, Wei Gan, Yaofeng Chen,* “Monoalkyl and monoanilide yttrium complexes containing tridentate pyridyl-1-azaallyl dianionic ligands” Dalton Trans. 2011, 40, 2366-2374. (Invited for the themed issue entitled “New Talent: Asia”).

16. 刘智潇, 陈耀峰,*  稀土金属有机化学的一个前沿领域:稀土卡宾化学中国科学(化学), 2011, 41, 304-313. (评述)

17. Erli Lu, Yuxue Li, Yaofeng Chen,* “A Scandium Terminal Imido Complex: Synthesis, Structure and DFT Studies” Chem. Commun., 2010, 46, 4469-4471. (封面文章)

18. Yuanyuan Yuan, Yaofeng Chen,* Guangyu Li, Wei Xia, “Synthesis and Structural Features of Boratabenzene Rare-earth Metal Alkyl Complexes” Organometallics 2010, 29, 3722-3728.

19. Xin Xu, Yaofeng Chen,* Jian Feng, Gang Zou, Jie Sun, “Half-sandwich Mono(indenyl) Rare-earth Metal Dialkyl Complexes: Syntheses, Structures and Catalytic Reactivities of  (1,3-(SiMe3)2C9H5)RE(CH2SiMe3)2(THF)Organometallics 2010, 29, 549-553.

20. Yangjian Hu, Xin Xu, Yuetao Zhang, Yaofeng Chen,* Eugene Y.-X. Chen,* “Polymerization of Naturally Renewable Methylene Butyrolactones by Half-Sandwich Indenyl Rare Earth Metal Dialkyls with Exceptional Activity” Macromolecules 2010, 43, 9328-9336.

21. Peng Cui, Yaofeng Chen,* Maxim V. Borzov, “Neodymium(III) Phosphinidene Complexes Supported by Pentamethylcyclopentadienyl and Hydrotris(pyrazolyl)borate Ligands” Dalton Trans. 2010, 39, 6886-6890. (Invited for the themed issue entitled “New Horizons in Organo-f-element Chemistry”)

22. Xin Xu, Yaofeng Chen,* Gang Zou, * Jie Sun, “Single, Double and Triple Deprotonation of a β-Diketimine Bearing Pendant Pyridyl Group and the Corresponding Rare-earth Metal Complexes” Dalton Trans. 2010, 39, 3952-3958.

23. Peng Cui, Yaofeng Chen,* Qiang Zhang, Guangyu Li, Wei Xia, “Synthesis, and Structural Characterization of Solvent-free Divalent Ytterbium Bis(boratabenzene) and (Cyclopentadienyl)(Boratabenzene) Complexes” J. Organomet. Chem. 2010, 695, 2713-2719. (Invited for the special issue of Organ-f-element Chemistry at Pacifichem 2010)

24. Erli Lu, Wei Gan, Yaofeng Chen,* “Monoalkyllanthanide Complexes with New b-Diketiminato Derivative Dianionic Ligands” Organometallics 2009, 28, 2318.

25. Xin Xu, Yaofeng Chen,* Jie Sun, “Indenyl Abstraction vs Alkyl Abstraction of (Indenyl)ScR2(THF) by [Ph3C][B(C6F5)4]: Aspecific and Syndiospecific Styrene Polymerization” Chem. Eur. J. 2009, 15, 846-850.

26. Peng Cui, Yaofeng Chen,* Guangyu Li, Wei Xia, “An ansa-Hetero-Borabenzene Divalent Lanthanide Amide via C-H Bond Cleavage” Angew. Chem. Int. Ed. 2008, 47, 9944-9947.

27. Peng Cui, Yaofeng Chen,* Xin Xu, Jie Sun, “An Unprecedented Lanthanide Phosphinidene Halide: Synthesis, Structure and Reactivity” Chem. Commun. 2008, 5547-5549.

28. Yuanyuan Yuan, Yaofeng Chen,* Guangyu Li, Wei Xia, “Reactions of Boratabenzene Yttrium Complexes with KN(SiMe3)2: Salt Elimination and p-Ligand Displacement” Organometallics 2008, 27, 6307-6312.

29. Peng Cui, Yaofeng Chen,* Guoping Wang, Guangyu Li, Wei Xia, “Divalent Ytterbium Boratabenzene Complex (C5H5BNPh2)2Yb(THF)2: Synthesis, Structure and Solvent-Mediated Redox Transformation” Organometallics 2008, 4, 4013-4016.

30. Xin Xu, Xiaoyan Xu, Yaofeng Chen,* Jie Sun, “Dialkyl lanthanide Metal Complexes Containing New Tridentate Monoanionic Ligands with Nitrogen Donors” Organometallics 2008, 27, 758-763.

31. Peng Cui, Yaofeng Chen,* Xiaohua Zeng, Jie Sun, Guangyu Li, Wei Xia, “Boratabenzene Derivatives of Divalent Samarium: Syntheses, Structures and Catalytic Reactivities of (C5H5BXPh2)2Sm(THF)2(X = N, P)” Organometallics 2007, 26, 6519-6521.