黄正 研究员

中国科学院上海有机化学研究所

金属有机化学国家重点实验室 

上海市零陵路345号,200032

电话: +86 21 54925522 

传真: +86 21 64166128

邮箱: huangzh@sioc.ac.cn

教育:

2004-2009  University of North Carolina at Chapel Hill,博士(导师:Prof. Maurice S. Brookhart)

2001-2004  南开大学化学系,硕士 (导师:卜显和教授)

1997-2001  南开大学化学系,学士

工作经历:

2011-   中国科学院上海有机化学研究金属有机国家重点实验室,研究员

2009-2011 Postdoctoral Research Associate, University of Illinois at Urbana-Champaign (导师:Prof. John F. Hartwig) 

研究领域:
  • 烯烃聚合: 着重于含极性官能团单体与非极性单体的共聚,设计过渡金属催化剂,合成新型高分子材料,研究聚合反应机理
  • 能源化学: 发展催化体系将低价值的化工产物、可再生的资源、以及对生态环境造成负面影响的物质材料转换为清洁的、易运输的液状燃油
  • 设计和合成用于有机转化的金属催化剂,侧重于第一列后过渡金属。表征金属化合物结构和性质,研究其反应活性和反应机理

职务:
课题组长,金属有机化学国家重点实验室副主任

代表论著:

 

1. Huang, Z.; Zhou, J. R.; Hartwig, J. F. "N-H Activation of Hydrazines by Iridium(I). Double N-H Activation to Form Iridium Aminonitrene Complexes" J. Am. Chem. Soc. 2010, 132, 11458-11460.

2. Huang, Z.; White, P. S.; Brookhart, M. "Ligand Exchanges and Selective Catalytic Hydrogenation in Molecular Single Crystals" Nature 2010, 465, 598-601. (Highlighted in Chemical & Engineering News, Chemistry World, and Nature Chemistry)

3. Huang, Z.; Rolfe, E.; Carson, E. C.; Brookhart, M.; Goldman, A. S.; El-Khalafy, S. H.; MacArthur, A. H. R. "Efficient Heterogeneous Dual Catalyst Systems for Alkane Metathesis" Adv. Synth. & Catal. 2010, 352, 125-135.

4. Huang, Z.; Brookhart, M.; Goldman, A. S.; Kundu, S.; Ray, A.; Scott, S. L.; Vicente, B. C. "Highly Active and Recyclable Heterogeneous Iridium Pincer Catalysts for Transfer Dehydrogenation of Alkanes" Adv. Synth. & Catal. 2009, 351, 188-206.

5. Goldman, A. S.; Roy, A. H.; Huang, Z.; Ahuja, R.; Schinski, W.; Brookhart, M. "Catalytic Alkane Metathesis by Tandem Alkane Dehydrogenation Olefin Metathesis" Science 2006, 312, 257-261.

(Highlighted in Nature, Science, National Geographic News, Scientific American, Science Daily, Discover magazine…)

6. Huang, Z.; Song, H. B.; Du, M.; Chen, S. T.; Bu, X. H.; Ribas, J. "Coordination Polymers Assembled from Angular Dipyridyl Ligands and Cu(II), Cd(II), Co(II) Salts: Crystal Structures and Properties" Inorg. Chem. 2004, 43, 931-944.

7. Huang, Z.; Du, M.; Song, H. B.; Bu, X. H. "Effect of Anions on the Framework Formation of Novel Ag(I) Coordination Polymers with Angular Bridging Ligands" Crystal Growth & Design 2004, 4, 71-78.