王晓明 研究员

中国科学院上海有机化学研究所 

金属有机化学国家重点实验室  

上海市零陵路345号,200032 

电话: +86 21 54925578

邮箱: xiaoming@sioc.ac.cn 

 

简介:

20193月:研究员,中科院上海有机所金属有机国家重点实验室 

20182-20193月:博士后,日本东京大学工学院Kyoko Nozaki教授 

20149-20181月:洪堡学者,博士后,德国明斯特大学Frank Glorius教授 

20099-20147月:硕博研究生,中国科学院上海有机化学研究所 

20059-20097月:理学学士,浙江大学 

 

研究领域:

本人具有在过渡金属催化的不对称反应、合成方法学和烯烃聚合等领域的研究经历,在新型催化剂的创制、方法学发展和机理研究方面具有丰富的研究经验。本课题组将致力于新型金属络合物的制备及其催化性能研究。 

 

获奖及荣誉: 

2013年博士研究生国家奖学金 

2014年度中国科学院院长特别奖 

2015年度中国科学院优秀博士学位论文 

德国洪堡博士后奖学金 

2020年度“Thieme Chemistry Journals Award”国际学术奖 

 

代表性论文:

1. Wang, X.; Seidel, F. W.; Nozaki, K.* Angew. Chem. Int. Ed. 201958, 12955–12959. Synthesis of Polyethylene with in-chain α,β-Unsaturated Ketone and Isolated Ketone Units by Pd-catalyzed Ring-opening Copolymerization of Cyclopropenones with Ethylene. 

2. Wang, X.; Nozaki, K.* .J. Am. Chem. Soc. 2018140, 15635-15640. Selective Chain-end Functionalization of Polar Polyethylenes: Orthogonal Reactivity of Carbene and Polar Vinyl Monomers in Their Copolymerization with Ethylene. 

3. Wang, X.;& Li, Y.;& Knecht, T.; Daniliuc, C. G.; Houk, K. N.*; Glorius, F.* (&Both authors contributed equally.) Angew. Chem. Int. Ed. 201857, 5520-5524. Unprecedented Dearomatized Spirocyclopropane in a Sequential Rh(III)-catalyzed C-H Activation and Rearrangement Reaction. 

4. Wang, X.; Lerchen, A.; Daniliuc, C. G.; Glorius, F.* Angew. Chem. Int. Ed. 201857, 1712-1716. Efficient Synthesis of Arylated Furans Enabled by a Sequential Rh-catalyzed Arylation and Cycloisomerization of Cyclopropenes. 

5. Wang, X.; Gensch, T.; Lerchen, A.; Daniliuc, C. G.; Glorius, F.* J. Am. Chem. Soc. 2017139, 6506-6512 (Top 20 most read JACS papers in May, 2017. Highlighted by Chemistry Views). Cp*Rh(III)/Bicyclic Olefin Cocatalyzed C-H Bond Amidation by Intramolecular Amide Transfer. 

6. Wang, X.; Lerchen, A.; Gensch, T.; Knecht, T.; Daniliuc, C. G.; Glorius, F.* Angew. Chem. Int. Ed. 201756, 1381-1384. Combination of Cp*RhIII-Catalyzed C-H Activation and a Wagner–Meerwein-Type Rearrangement. 

7. Wang, X.; & Yu, D.-G.; & Glorius, F.* (&Both authors contributed equally.) Angew. Chem. Int. Ed. 201554, 10280. Cp*Rh(III)-Catalyzed Arylation of sp3 C-H Bonds. 

8. Wang, X.; Guo, P.; Han, Z.; Wang, X.; Wang, Z.; Ding, K.* J. Am. Chem. Soc. 2014136, 405-411. Spiroketal-Based Diphosphine Ligands in Pd-Catalyzed Asymmetric Allylic Amination of Morita-Baylis-Hillman Adducts: Exceptionally High Efficiency and New Mechanism. 

9. Wang, X.; Meng, F.; Wang, Y.; Han, Z.; Chen, Y.-J.; Liu, L.*; Wang, Z.*; Ding, K.* Angew. Chem. Int. Ed. 201251, 9276-9282 (Highlighted by SYNFACTS2012, 1286). Aromatic Spiroketal Bisphosphine Ligands: Palladium-Catalyzed Asymmetric Allylic Amination of Racemic Morita–Baylis–Hillman Adducts. 

10. Wang, X.; Han, Z.; Wang, Z.*; Ding, K.* Angew. Chem. Int. Ed. 201251, 936-940 (Highlighted by Angew. Chem. Int. Ed. 201251, 9486-9488 and SYNFACTS2012, 412). Catalytic Asymmetric Synthesis of Aromatic Spiroketals by SpinPhox/Iridium(I)-Catalyzed Hydrogenation and Spiroketalization of α,α’-Bis(2-hydroxyarylidene)-Ketones.