韩秀玲 副研究员

中国科学院上海有机化学研究所

金属有机化学国家重点实验室 

上海市零陵路345号,200032

电话: +86 21 54925153

传真: +86 21 64166128

邮箱:xlhan@sioc.ac.cn

教育:

2007.09 - 2010.07  苏州大学材料化学学部,博士(在职,导师:陆熙炎)

1993.09 - 1996.07  华东师范大学化学系,硕士(导师:吴斌才教授)

1989.09 - 1993.07  南京师范大学化学系,学士

工作经历:

2006.06 -     中国科学院上海有机化学研究所金属有机国家重点实验室,副研究员

1999.06 - 2006.06  中国科学院上海有机化学研究所金属有机国家重点实验室,助理研究员

1996.07 - 1999.06  中国科学院上海有机化学研究所金属有机国家重点实验室,研究实习员

 

研究领域:

两价钯催化的化学反应研究

代表论著:

1.Wang, H.;Han, X.*; Lu, X.* Pd(II)-Catalyzed Annulation of N-Benzyl-N-Aroylmethyl-2- Alkynamides with Arylboronic Acids: An Efficient Synthesis of Highly Substituted α-Alkylidene-β-Hydroxy-γ-Lactams.Tetrahedron2010, 66, 9129-9134.

2.Han, X.; Lu, X.* Cationic Pd(II)-Catalyzed Tandem Reaction of 2-Arylethynylanilines and Aldehydes: An Efficient Synthesis of Substituted3-Hydroxymethyl Indoles Org. Lett.2010, 12, 3336-3339.

3.Han, X.; Lu, X.* Control of Chemoselectivity by Counteranions of Cationic Palladium Complexes: A Convenient Enantioselective Synthesis of Dihydrocoumarins Org. Lett.2010, 12, 108-111.

4.Han, X.; Lu, X.* Novel Palladium-Catalyzed Acyloxylation/Cyclization of 2-(3’-Alkenyl)indoles.Org. Lett.2009,11, 2381-2384.

5.Feng, J.; Lu, X.*; Kong, A.;Han, X.A Highly Regio- and Stereo-Selective [3+2] Annulation of Allylic Compounds and 2-Substituted1,1-Dicyanoalkenes through a Catalytic Carbon–Phosphorus Ylide Reaction.Tetrahedron2007, 63, 6035-6041.

6.Kong, A.;Han, X.; Lu, X.* Highly Efficient Construction of Benzene Ring in Carbazoles by Palladium-Catalyzed Endo-Mode Oxidative Cyclization of 3-(3’-Alkenyl)indoles.Org. Lett.2006, 8, 1339-1343.

7.韩秀玲,刘桂霞,陆熙炎* 钯催化反应中的β-氢消除反应。有机化学,2005, 25, 1182-1197.

8.Du, Y.;Han, X.; Lu, X.* Alkaloids-Catalyzed Regio- and Enantioselective Allylic Nucleophilic Substitution oftert-Butyl Carbonate of the Morita-Baylis-Hillman Products

Tetrahedron Lett.2004, 45, 4967-4971.

9.Zhang, Q.; Lu, X.;*Han, X.Palladium(II)-Catalyzed Asymmetric Cyclization of (Z)-4’-Acetoxy-2’-butenyl 2-Alkynoates. Role of Nitrogen-Containing Ligands in Palladium(II)-Mediated Reactions.J. Org. Chem.2001,66, 7676-7684.

10.Zhang, Z.; Lu, X.*; Xu, Z.; Zhang, Q.;Han, X.Role of Halide Ions in Divalent Palladium Mediated Reactions: Competition between β-Heteroatom Elimination and β-Hydride Elimination of a Carbon-Palladium Bond.Organometallics2001, 20, 3724-3728.